WebMar 30, 2024 · Characterizing Diamylamylphosphonate (DAAP) as an Americium Ligand for Nuclear Fuel-Cycle Applications B. Mincher, N. Schmitt, R. D. Tillotson, G. Elias, B. White, J. Law Chemistry 2014 Successful deployment of the currently-envisioned advanced nuclear fuel cycle requires the development of a partitioning scheme to separate Am … WebOxidation of Am to higher oxidation states is one option to achieve such a separation. Hexavalent Am has now been routinely prepared in our laboratory in strongly acidic …
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WebFrom this solution uranium was separated to >99.9 % in a primary solvent extraction cycle using 1.0 mol/L DEHiBA ( N, N -di (2-ethylhexyl)isobutyramide in TPH (hydrogenated tetrapropene) as the organic phase. The raffinate solution from this process, containing 10 g/L Pu, was further processed in a second cycle of solvent extraction. WebOct 1, 2007 · Abstract Dibutyl phenyl phosphonate (DBPP) was synthesized by the reaction of phenyl phosphorochloridate with 1-butanol in dichloromethane, in the presence of pyridine as a base. The product was… Expand 8 Extraction studies of actinides and lanthanides by bifunctional H-phosphonates grasshopper creek montana
Characterizing Diamylamylphosphonate (DAAP) as an …
WebNov 6, 2015 · This simple electrochemical procedure provides a method to access the higher oxidation states of Am in noncomplexing media for the study of the associated coordination chemistry and, more important, for more efficient separation protocols. WebMar 23, 2012 · Diamylamylphosphonate Solvent Extraction of Am(VI) from Nuclear Fuel Raffinate Simulant Solution Bruce J. Mincher Aqueous Separations and Radiochemistry … WebJan 24, 2014 · Characterizing Diamylamylphosphonate (DAAP) as an Americium Ligand for Nuclear Fuel-Cycle Applications DOI: Authors: Bruce J. Mincher Nicholas C. Schmitt Richard D. Tillotson Gracy Elias Request... grasshopper creek montana fishing